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(c) Schematic drawing of the opposite effect of temperature and pressure on the swollen-to-collapsed transition of the PNIPAM polymer (after ) a 0 b c pkbar temperature pressure 80 60 40 20 80 60 40 20 10 20 30 40 50 60 T°C Relative area Relative area 0 02468 The negative V o value indicates the presence of significant void June 12 Forex in the collapsed state.
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