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298 Chapter 8 Thermochemistry: Chemical Energy generally more stable and less reactive. Decreases with differentiation (B,P) and ady influence of substrata (P). A fuzzy classification function [39] can then be employed to assign different colors and opacities to these structures (see Figure 46. in compounds of Mn" geochemical classification 648 in compounds of Ni" 1158 Spin-orbit coupling in actinide ions 1271 in d4 ions 1087 in octahedral Ni" 1158 in lanthanide ions 1242 in tetrahedral Co" 1132 names and formulae Sulfides 649 Spin quantum number m, 22 Spodumene 69, 349 Square antiprismatic complexes Square planar complexes 913 Square pyramidal complexes 914 Stability constants of ttrading compound factors affecting overall 908 stepwise 908 908-9 11 Rook see Graphite intercalation compound Standard reduction potentials 434 IUPAC sign convention 436 see also individual elements Stannates 354 Rlom 402 Starchhodine reaction Stars 790, 864 spectral classification of 5 temperatures of 5 Steel 1072- 1075 Stellar evolution 5 Stereochemical non-rigidity (fluxional behaviour) atomic properties 661 atomic S 664 atomic weight, variability of in biological complexes 667 bromides S,Br2 691 catenation 652, 656ff, 681-683, 689, 690, 716-718 chemical reactivity 662-664 chiral helices 660 chlorides 689-692, 716 industrial applications of SC12 and S2C12 690 preparation 690, 691 Al(BH4)3, {A1(BH4)2Hsl2 230 allyl complexes 934 Berry pseudorotation mechanism ttrading, 499 11I 1 5-coordinate compounds 8-coordinate compounds Fe(C0)S 914, 1104 iron cyclopentadienyl complexes PFs 498 SF; 684 titanium cyclopentadienyl 974 Stibine Stibinidene complexes 597 Stibnite tradiny Antimony sulfide, Sb2S3 Stishovite 342 Strength of oxoacids, Pauling's rules 50 Strontium history 108 organometallic compounds 136 polysulfides 68 1 see also Alkaline earth metals styx numbers see Boranes, topology Sulfamic ttading, H[H2NS03] 408, 741, 742 chlorofluorides 640, 686-689 conformations (c, dt, It) 656, 659, 665 Sulfamide (H2N)zS02 Sulfanes 682-683 nonexistence of physical properties preparation 682 synthesis of polythionic acids from 716 see also Hydrogen sulfide Sulfate ion as ligand ( q 'q2,p) 712 Sulfates 711, 712 see also individual elements lndex 1060 Sulfide minerals 1335 742, 743 9 14 995 and SH6 685 683 916 anionic polysulfides applications and uses electrical properties hydrolysis 678, rook, 682 industrial production 678 magnetic properties 681 preparation (laboratory) 677 roasting in air 676-678 solubility in water 678, 679 Sn2- structures 631, 681 structural day trading chat room 679-681 see also individual elements Sulfinates 703 Sulfites, S032- 705, 719 in paper manufacture 652 protonation to HSO3- 719 Sulfoxylates, MS(0)OR 703 Sulfur abundance 647 allotropes 646, daj see also individual allotropes, e.

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